Chelsea manager Jose Mourinho will take charge of the Rest of the World team against England for Soccer Aid 2014 at Old Trafford next month.
The Portuguese boss has agreed to coach ex-players including Edwin van der Sar and Jaap Stam, as well as actors James McAvoy and Jeremy Renner and celebrity chef Gordon Ramsay.
The friendly match, which will take place at Manchester United's home ground, is in aid of children's organisation UNICEF and will get underway on Sunday, June 8.
England, who will be led by singer Robbie Williams and managed by West Ham United boss Sam Allardyce, will feature former players Jamie Carragher and Teddy Sheringham within the side, as well as actor Damian Lewis and comedian Jack Whitehall.
Mourinho said: "I'm looking forward to beating Robbie Williams's and Big Sam's England team and raising money for UNICEF."
The event will be broadcast on ITV and hosted by Dermot O'Leary and Sky Sports presenter Kirsty Gallacher.